Interaction

curated

Interaction Scheme

Molecule

Untitled
Anthracene

c = 0.0 — 10.0 µM

Host

Cb8
CB8

c = 5.0 µM

Cofactor

Methyl viologen
Methyl viologen

c = 5.0 µM

Binding Properties

𝜈 Molecule 1 : 1 Host
Ka = 1.60⋅106 ± 3.00⋅105 M-1
Kd =
logKa = 6.2 ± 0.08
T 25.0 °C ≈ 298 K
Energy kJ mol-1 kcal mol-1
ΔG = -35.41 ± 0.47 -8.46 ± 0.11
Comment
on surface of Au nanoparticles; Anthracene added from 1 mM stock in MeOH
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Associative Binding Assay
Technique: Surface Enhanced Raman Scattering
Detailed information about the solvation.
Solvent System Single Solvent
Solvent water
pH 7.0
Please find here information about the dataset this interaction is part of.
Citation:

S. Kasera, J. J. Baumberg, O. A. Scherman, F. Biedermann, S. Mahajan, SupraBank 2024, Quantitative SERS Using the Sequestration of Small Molecules Inside Precise Plasmonic Nanoconstructs (dataset). https://doi.org/10.34804/supra.20220702457

Link: https://doi.org/10.34804/supra.20220702457
Export: BibTex | RIS | EndNote
Please find here information about the scholarly article describing the results derived from that data.
Citation:

S. Kasera, F. Biedermann, J. J. Baumberg, O. A. Scherman, S. Mahajan, Nano Lett. 2012, 12, 5924–5928.

Link: https://doi.org/10.1021/nl303345z
Export: BibTex | RIS | EndNote |

Binding Isotherm Simulations

The plot depicts the binding isotherm simulation of a 1:1 interaction of Anthracene (1.25e-05 M) and CB8 (0 — 2.5e-05 M).