Interaction Scheme
Molecule
L-Ornithine
c = 0.0 — 1000.0 µM
Host
Napthalene-monofunctionalized CB6
c = 3.0 µM
Indicator
Europium trinitrate hexahydrate
c = 300.0 µM
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka = | 990.0 | ± 198.0 | M-1 |
| Kd = | |||
| logKa = | |||
| T | 25.0 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -17.1 | ± 0.5 | -4.09 | ± 0.12 |
These are the specifications of the determination of the experimental results.
| Detection Method: | Competitive | |||
| Assay Type: | Competitive Binding Assay | |||
| Technique: | Fluorescence | |||
| 𝛌ex | = | 266.0 nm | ||
| 𝛌em | = | 319.0 nm | ||
Detailed information about the solvation.
| Solvent System | Single Solvent |
| Solvent | water |
| pH | 7.0 |
Please find here information about the dataset this interaction is part of.
| Citation: |
T. Minami, N. A. Esipenko, B. Zhang, L. Isaacs, P. Anzenbacher, SupraBank 2025, “Turn-on” fluorescent sensor array for basic amino acids in water (dataset). https://doi.org/10.34804/supra.202109281 |
| Link: | https://doi.org/10.34804/supra.202109281 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
T. Minami, N. A. Esipenko, B. Zhang, L. Isaacs, P. Anzenbacher, Chem. Commun. 2014, 50, 61–63. |
| Link: | https://doi.org/10.1039/c3cc47416j |
| Export: | BibTex | RIS | EndNote | |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of L-Ornithine (0.020202020202020204 M) and Napthalene-monofunctionalized CB6 (0 — 0.04040404040404041 M).
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