Interaction Scheme

Molecule

Ru%28bpy%292dppz
[Ru(bpy)2dppz]2+

c = 7.5 µM

Host

Cb7
CB7

c = 0.0 — 1500.0 µM

Binding Properties

𝜈 Molecule 1 : 1 Host
Ka = 2800.0 M-1
Kd =
logKa = 3.45
T 25.0 °C 298 K
Energy kJ mol-1 kcal mol-1
ΔG = -19.68 -4.7
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Direct Binding Assay
Technique: Fluorescence
𝛌ex = 450.0 nm
𝛌em = 608.0 nm
Detailed information about the solvation.
Solvent System Single Solvent
Solvent water
pH 6.9
Please find here information about the dataset this interaction is part of.
Citation:

M. Shinde, S. Rao, S. Gejji, A. Kumbhar, SupraBank 2024, Distinct photophysical behaviour and transport of cell-impermeable [Ru(bpy)2dppz]2+ in live cells using cucurbit[7]uril as a delivery system (dataset). https://doi.org/10.34804/supra.20210928289

Link: https://doi.org/10.34804/supra.20210928289
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Please find here information about the scholarly article describing the results derived from that data.
Citation:

M. N. Shinde, S. S. Rao, S. P. Gejji, A. A. Kumbhar, Dalton Trans. 2018, 47, 3857–3863.

Link: https://doi.org/10.1039/c7dt04230b
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Binding Isotherm Simulations


The plot depicts the binding isotherm simulation of a 1:1 interaction of [Ru(bpy)2dppz]2+ (0.007142857142857143 M) and CB7 (0 — 0.014285714285714285 M).