Interaction Scheme
Molecule
Ferrocene
c = 820.0 µM
Host
CB7
c = 0.0 — 870.0 µM
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka > | 1.00⋅106 | M-1 | |
| Kd > | |||
| logKa > | |||
| T | 25.0 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | < | -34.25 | -8.19 |
These are the specifications of the determination of the experimental results.
| Detection Method: | Direct | ||
| Assay Type: | Direct Binding Assay | ||
| Technique: | Potentiometry | ||
Detailed information about the solvation.
| Solvent System | Complex Mixture | |
| Solvents | water | |
| Additives | sodium chloride | 100.0 mM |
| Total concentration | 100.0 mM |
Please find here information about the dataset this interaction is part of.
| Citation: |
A. E. Kaifer, W. Ong, SupraBank 2025, Unusual Electrochemical Properties of the Inclusion Complexes of Ferrocenium and Cobaltocenium with Cucurbit[7]uril (dataset). https://doi.org/10.34804/supra.20210928321 |
| Link: | https://doi.org/10.34804/supra.20210928321 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
W. Ong, A. E. Kaifer, Organometallics 2003, 22, 4181–4183. |
| Link: | https://doi.org/10.1021/om030305x |
| Export: | BibTex | RIS | EndNote | |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of Ferrocene (2.0e-05 M) and CB7 (0 — 4.0e-05 M).
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