Interaction

curated

Interaction Scheme

Molecule

Ferrocene
Ferrocene

c = 820.0 µM

Host

Cb7
CB7

c = 0.0 — 870.0 µM

Binding Properties

𝜈 Molecule 1 : 1 Host
Ka > 1.00⋅106 M-1
Kd >
logKa > 6.0
T 25.0 °C ≈ 298 K
Energy kJ mol-1 kcal mol-1
ΔG < -34.25 -8.19
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Direct Binding Assay
Technique: Potentiometry
Detailed information about the solvation.
Solvent System Complex Mixture
Solvents water
Additives sodium chloride 100.0 mM
Total concentration 100.0 mM
Please find here information about the dataset this interaction is part of.
Citation:

A. E. Kaifer, W. Ong, SupraBank 2024, Unusual Electrochemical Properties of the Inclusion Complexes of Ferrocenium and Cobaltocenium with Cucurbit[7]uril (dataset). https://doi.org/10.34804/supra.20210928321

Link: https://doi.org/10.34804/supra.20210928321
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Please find here information about the scholarly article describing the results derived from that data.
Citation:

W. Ong, A. E. Kaifer, Organometallics 2003, 22, 4181–4183.

Link: https://doi.org/10.1021/om030305x
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Binding Isotherm Simulations

The plot depicts the binding isotherm simulation of a 1:1 interaction of Ferrocene (2.0e-05 M) and CB7 (0 — 4.0e-05 M).