Interaction Scheme
Molecule
Cobaltocene hexafluorophosphate
c = 16.3 µM
Host
CB8
c = 0.0 — 30.0 µM
Indicator
1-Adamantylammonium
c = 30.0 µM
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka = | 1.90⋅108 | M-1 | |
| Kd = | |||
| logKa = | |||
| T | 25.0 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -47.26 | -11.3 |
These are the specifications of the determination of the experimental results.
| Detection Method: | Competitive | |||
| Assay Type: | Competitive Binding Assay | |||
| Technique: | Absorbance | |||
| 𝛌abs | = | 261.0 nm | ||
Detailed information about the solvation.
| Solvent System | Complex Mixture | |
| Solvents | water | |
| Additives | Sodium acetate | 50.0 mM |
| Total concentration | 50.0 mM |
Please find here information about the dataset this interaction is part of.
| Citation: |
A. E. Kaifer, S. Yi, SupraBank 2024, Determination of the Purity of Cucurbit[n]uril (n = 7, 8) Host Samples (dataset). https://doi.org/10.34804/supra.20210928197 |
| Link: | https://doi.org/10.34804/supra.20210928197 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
S. Yi, A. E. Kaifer, J. Org. Chem. 2011, 76, 10275–10278. |
| Link: | https://doi.org/10.1021/jo2018312 |
| Export: | BibTex | RIS | EndNote | |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of Cobaltocene hexafluorophosphate (1.0526315789473685e-07 M) and CB8 (0 — 2.105263157894737e-07 M).
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