𝜈 | Molecule 1 : 1 Host | ||
Ka = | 2600.0 | ± 330.0 | M-1 |
Kd = | |||
logKa = | |||
T | 25.0 °C | ||
Energy | kJ mol-1 | kcal mol-1 | |||
---|---|---|---|---|---|
ΔG | = | -19.49 | ± 0.32 | -4.66 | ± 0.08 |
ΔH | = | -27.78 | ± 0.75 | -6.64 | ± 0.18 |
-TΔS | = | 8.28 | ± 1.05 | 1.98 | ± 0.25 |
J mol-1 K-1 | cal mol-1 K-1 | ||||
ΔS | = | -27.8 | ± 3.5 | -6.6 | ± 0.8 |
Detection Method: | Direct | ||
Assay Type: | Direct Binding Assay | ||
Technique: | Isothermal Titration Calorimetry | ||
Molecule: | syringe | ||
Partner: | cell |
Solvent System | Buffer System | 50 mM phosphate buffer with NaCl & urea, pH 8.6 |
Solvents | water | |
Additives | urea | 8000.0 mM |
sodium chloride | 100.0 mM | |
phosphate | 50.0 mM | |
Source of Concentration | real | |
Total concentration | 8150.0 mM | |
pH | 8.6 |
Citation: |
A. E. Kaifer, L. A. Godínez, L. Schwartz, C. M. Criss, SupraBank 2024, Thermodynamic Studies on the Cyclodextrin Complexation of Aromatic and Aliphatic Guests in Water and Water−Urea Mixtures. Experimental Evidence for the Interaction of Urea with Arene Surfaces (dataset). https://doi.org/10.34804/supra.2021092880 |
Link: | https://doi.org/10.34804/supra.2021092880 |
Export: | BibTex | RIS | EndNote |
Citation: |
L. A. Godínez, L. Schwartz, C. M. Criss, A. E. Kaifer, J. Phys. Chem. B 1997, 101, 3376–3380. |
Link: | https://doi.org/10.1021/jp970359i |
Export: | BibTex | RIS | EndNote | |
The plot depicts the binding isotherm simulation of a 1:1 interaction of 1-adamantane carboxylate (0.007692307692307693 M) and β-CD (0 — 0.015384615384615385 M).