𝜈 | Molecule 1 : 1 Host | ||
Ka = | 3990.0 | ± 1165.0 | M-1 |
Kd = | |||
logKa = | |||
T | 25.0 °C | ||
Energy | kJ mol-1 | kcal mol-1 | |||
---|---|---|---|---|---|
ΔG | = | -20.55 | ± 0.75 | -4.91 | ± 0.18 |
ΔH | = | -1.7 | ± 0.08 | -0.41 | ± 0.02 |
-TΔS | = | -18.87 | ± 2.22 | -4.51 | ± 0.53 |
J mol-1 K-1 | cal mol-1 K-1 | ||||
ΔS | = | 63.3 | ± 7.4 | 15.1 | ± 1.8 |
Detection Method: | Direct | ||
Assay Type: | Direct Binding Assay | ||
Technique: | Isothermal Titration Calorimetry | ||
Molecule: | syringe | ||
Partner: | cell |
Solvent System | Buffer System | 50 mM phosphate buffer with NaCl & urea, pH 8.6 |
Solvents | water | |
Additives | urea | 8000.0 mM |
sodium chloride | 100.0 mM | |
phosphate | 50.0 mM | |
Source of Concentration | real | |
Total concentration | 8150.0 mM | |
pH | 8.6 |
Citation: |
A. E. Kaifer, L. A. Godínez, L. Schwartz, C. M. Criss, SupraBank 2024, Thermodynamic Studies on the Cyclodextrin Complexation of Aromatic and Aliphatic Guests in Water and Water−Urea Mixtures. Experimental Evidence for the Interaction of Urea with Arene Surfaces (dataset). https://doi.org/10.34804/supra.2021092880 |
Link: | https://doi.org/10.34804/supra.2021092880 |
Export: | BibTex | RIS | EndNote |
Citation: |
L. A. Godínez, L. Schwartz, C. M. Criss, A. E. Kaifer, J. Phys. Chem. B 1997, 101, 3376–3380. |
Link: | https://doi.org/10.1021/jp970359i |
Export: | BibTex | RIS | EndNote | |
The plot depicts the binding isotherm simulation of a 1:1 interaction of 2-naphtalenecarboxylate (0.005012531328320802 M) and β-CD (0 — 0.010025062656641603 M).