Interaction Scheme
Molecule
(-)-camphor
c = 2000.0 µM
Host
α-CD
c = 0.0 — 1290.0 µM
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka = | 4.49⋅105 | M-1 | |
| Kd = | |||
| logKa = | |||
| T | 20.42 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -31.17 | -7.45 | ||
| ΔH | = | -65.56 | -15.67 | ||
| -TΔS | = | 33.79 | 8.08 | ||
| J mol-1 K-1 | cal mol-1 K-1 | ||||
| ΔS | = | -115.1 | -27.5 | ||
These are the specifications of the determination of the experimental results.
| Detection Method: | Direct | ||
| Assay Type: | Direct Binding Assay | ||
| Technique: | Isothermal Titration Calorimetry | ||
| Molecule: | syringe | ||
| Partner: | syringe | ||
Detailed information about the solvation.
| Solvent System | Single Solvent |
| Solvent | water |
Please find here information about the dataset this interaction is part of.
| Citation: |
F. P. Schmidtchen, SupraBank 2024, The Anatomy of the Energetics of Molecular Recognition by Calorimetry: Chiral Discrimination of Camphor by α-Cyclodextrin (dataset). https://doi.org/10.34804/supra.20210928110 |
| Link: | https://doi.org/10.34804/supra.20210928110 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
F. P. Schmidtchen, Chemistry - A European Journal 2002, 8, 3522. |
| Link: | https://doi.org/10.1002/1521-3765(20020802)8:15%3C3522::AID-CHEM3522%3E3.0.CO;2-X |
| Export: | BibTex | RIS | EndNote |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of (-)-camphor (4.4543429844097995e-05 M) and α-CD (0 — 8.908685968819599e-05 M).
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