Interaction Scheme
Molecule
(+)-camphor
c = 2000.0 µM
Host
α-CD
c = 0.0 — 1600.0 µM
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka = | 5.44⋅105 | M-1 | |
| Kd = | |||
| logKa = | |||
| T | 30.13 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -32.23 | -7.7 | ||
| ΔH | = | -75.14 | -17.96 | ||
| -TΔS | = | 41.86 | 10.0 | ||
| J mol-1 K-1 | cal mol-1 K-1 | ||||
| ΔS | = | -138.0 | -33.0 | ||
These are the specifications of the determination of the experimental results.
| Detection Method: | Direct | ||
| Assay Type: | Direct Binding Assay | ||
| Technique: | Isothermal Titration Calorimetry | ||
| Molecule: | syringe | ||
| Partner: | syringe | ||
Detailed information about the solvation.
| Solvent System | Single Solvent |
| Solvent | Deuterium Oxide |
Please find here information about the dataset this interaction is part of.
| Citation: |
F. P. Schmidtchen, SupraBank 2024, The Anatomy of the Energetics of Molecular Recognition by Calorimetry: Chiral Discrimination of Camphor by α-Cyclodextrin (dataset). https://doi.org/10.34804/supra.20210928110 |
| Link: | https://doi.org/10.34804/supra.20210928110 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
F. P. Schmidtchen, Chemistry - A European Journal 2002, 8, 3522. |
| Link: | https://doi.org/10.1002/1521-3765(20020802)8:15%3C3522::AID-CHEM3522%3E3.0.CO;2-X |
| Export: | BibTex | RIS | EndNote |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of (+)-camphor (3.676470588235294e-05 M) and α-CD (0 — 7.352941176470588e-05 M).
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