Interaction

curated

Interaction Scheme

Molecule

Untitled
Ru(II)[phen]3

Host

Cb10
CB10

Binding Properties

𝜈 Molecule 1 : 1 Host
Ka = 8.00⋅107 M-1
Kd =
logKa = 7.9
T 25.0 °C ≈ 298 K
Energy kJ mol-1 kcal mol-1
ΔG = -45.11 -10.78
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Direct Binding Assay
Technique: Fluorescence
𝛌em = 590.0 nm
Ibound⁄Ifree = 0.1
Detailed information about the solvation.
Solvent System Single Solvent
Solvent water
Please find here information about the dataset this interaction is part of.
Citation:

K. M. Anis-Ul-Haque, C. Woodward, A. Day, L. Wallace, SupraBank 2024, Interaction of the Large Host Q[10] with Metal Polypyridyl Complexes: Binding Modes and Effects on Luminescence (dataset). https://doi.org/10.34804/supra.20210928279

Link: https://doi.org/10.34804/supra.20210928279
Export: BibTex | RIS | EndNote
Please find here information about the scholarly article describing the results derived from that data.
Citation:

K. M. Anis-Ul-Haque, C. E. Woodward, A. I. Day, L. Wallace, Inorg. Chem. 2020, 59, 3942–3953.

Link: https://doi.org/10.1021/acs.inorgchem.9b03603
Export: BibTex | RIS | EndNote |

Binding Isotherm Simulations

The plot depicts the binding isotherm simulation of a 1:1 interaction of Ru(II)[phen]3 (2.5e-07 M) and CB10 (0 — 5.0e-07 M).