Interaction

curated

Interaction Scheme

Molecule

Untitled
Ru(II)[phen]3

Host

Cb10
CB10

Binding Properties

𝜈 Molecule 2 : 1 Host
Ka = 4.00⋅1014 M-2
Kd =
logKa = 14.6
T 25.0 °C ≈ 298 K
Energy kJ mol-1 kcal mol-1
ΔG = -83.35 -19.92
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Direct Binding Assay
Technique: Fluorescence
𝛌em = 590.0 nm
Ibound⁄Ifree = 0.1
Detailed information about the solvation.
Solvent System Single Solvent
Solvent water
Please find here information about the dataset this interaction is part of.
Citation:

K. M. Anis-Ul-Haque, C. Woodward, A. Day, L. Wallace, SupraBank 2024, Interaction of the Large Host Q[10] with Metal Polypyridyl Complexes: Binding Modes and Effects on Luminescence (dataset). https://doi.org/10.34804/supra.20210928279

Link: https://doi.org/10.34804/supra.20210928279
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Please find here information about the scholarly article describing the results derived from that data.
Citation:

K. M. Anis-Ul-Haque, C. E. Woodward, A. I. Day, L. Wallace, Inorg. Chem. 2020, 59, 3942–3953.

Link: https://doi.org/10.1021/acs.inorgchem.9b03603
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Binding Isotherm Simulations

The plot depicts the binding isotherm simulation of a 1:1 interaction of Ru(II)[phen]3 (5.0e-14 M) and CB10 (0 — 1.0e-13 M).