Interaction Scheme
Molecule
[Ir(ppy-CH2NH2Bu)2(bpy)]3+
c = 7.6 µM
Host
CB10
c = 48.0 µM
Binding Properties
| 𝜈 | Molecule 2 : 1 Host | ||
| Ka = | 3.50⋅1012 | ± 0.5 | M-2 |
| Kd = | |||
| logKa = | |||
| T | 25.0 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -71.6 | ± 0.0 | -17.11 | ± 0.0 |
These are the specifications of the determination of the experimental results.
| Detection Method: | Direct | |||
| Assay Type: | Direct Binding Assay | |||
| Technique: | Fluorescence | |||
| 𝛌ex | = | 360.0 nm | ||
| 𝛌em | = | 514.0 nm | ||
Detailed information about the solvation.
| Solvent System | Buffer System | 50 mM acetate pH-4.7 |
| Source of Concentration | ||
| Total concentration | 50.0 mM | |
| pH | 4.7 |
Please find here information about the dataset this interaction is part of.
| Citation: |
C. Woodward, A. Day, L. Wallace, L. R. Alrawashdeh, M. P. Cronin, SupraBank 2024, Modelling the luminescence of iridium cyclometalated complexes encapsulated in cucurbituril (dataset). https://doi.org/10.34804/supra.20220628438 |
| Link: | https://doi.org/10.34804/supra.20220628438 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
L. R. Alrawashdeh, M. P. Cronin, A. I. Day, L. Wallace, C. E. Woodward, Analyst 2018, 143, 519–527. |
| Link: | https://doi.org/10.1039/C7AN01632H |
| Export: | BibTex | RIS | EndNote | |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of [Ir(ppy-CH2NH2Bu)2(bpy)]3+ (5.714285714285714e-12 M) and CB10 (0 — 1.1428571428571428e-11 M).
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