Interaction Scheme

Molecule

Untitled
1,5-Dihydroxynaphthalene

c = 0.0 — 10.0 µM

Host

Cb8
CB8

c = 5.0 µM

Cofactor

Methyl viologen
Methyl viologen

c = 5.0 µM

Binding Properties

𝜈 Molecule 1 : 1 Host
Ka = 1.70⋅105 ± 5.00⋅104 M-1
Kd =
logKa = 5.23 ± 0.13
T 25.0 °C 298 K
Energy kJ mol-1 kcal mol-1
ΔG = -29.86 ± 0.75 -7.14 ± 0.18
Comment
on surface of Au nanoparticles
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Associative Binding Assay
Technique: Surface Enhanced Raman Scattering
Detailed information about the solvation.
Solvent System Single Solvent
Solvent water
pH 7.0
Please find here information about the dataset this interaction is part of.
Citation:

S. Kasera, J. J. Baumberg, O. A. Scherman, F. Biedermann, S. Mahajan, SupraBank 2024, Quantitative SERS Using the Sequestration of Small Molecules Inside Precise Plasmonic Nanoconstructs (dataset). https://doi.org/10.34804/supra.20220702457

Link: https://doi.org/10.34804/supra.20220702457
Export: BibTex | RIS | EndNote
Please find here information about the scholarly article describing the results derived from that data.
Citation:

S. Kasera, F. Biedermann, J. J. Baumberg, O. A. Scherman, S. Mahajan, Nano Lett. 2012, 12, 5924–5928.

Link: https://doi.org/10.1021/nl303345z
Export: BibTex | RIS | EndNote |

Binding Isotherm Simulations


The plot depicts the binding isotherm simulation of a 1:1 interaction of 1,5-Dihydroxynaphthalene (0.00011764705882352942 M) and CB8 (0 — 0.00023529411764705883 M).