Interaction Scheme
Molecule
Potassium trifluoromethanesulfonate
c = 0.0 — 1000.0 µM
Host
Pt2-18C6
c = 100.0 µM
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka = | 3981.0 | M-1 | |
| Kd = | |||
| logKa = | |||
| T | 25.0 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -20.55 | -4.91 |
These are the specifications of the determination of the experimental results.
| Detection Method: | Direct | |||
| Assay Type: | Direct Binding Assay | |||
| Technique: | Fluorescence | |||
| 𝛌ex | = | 343.0 nm | ||
| 𝛌em | = | 595.0 nm | ||
Detailed information about the solvation.
| Solvent System | Single Solvent |
| Solvent | tetrahydrofuran |
Please find here information about the dataset this interaction is part of.
| Citation: |
F. Biedermann, S. Sinn, M. Vishe, A. Aliprandi, C. Besnard, J. Lacour, L. De Cola, SupraBank 2025, A Ratiometric Luminescent Switch Based on Platinum Complexes Tethered to a Crown-Ether Scaffold (dataset). https://doi.org/10.34804/supra.20220711458 |
| Link: | https://doi.org/10.34804/supra.20220711458 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
S. Sinn, F. Biedermann, M. Vishe, A. Aliprandi, C. Besnard, J. Lacour, L. De Cola, ChemPhysChem 2016, 17, 1829–1834. |
| Link: | https://doi.org/%2010.1002/cphc.201501171 |
| Export: | BibTex | RIS | EndNote |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of Potassium trifluoromethanesulfonate (0.005023863350916855 M) and Pt2-18C6 (0 — 0.01004772670183371 M).
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