𝜈 | Molecule 1 : 1 Host | ||
Ka = | 4677.0 | ± 648.0 | M-1 |
Kd = | |||
logKa = | |||
T | 25.0 °C | ||
Energy | kJ mol-1 | kcal mol-1 | |||
---|---|---|---|---|---|
ΔG | = | -20.95 | ± 0.35 | -5.01 | ± 0.08 |
ΔH | = | -13.1 | ± 0.5 | -3.13 | ± 0.12 |
-TΔS | = | -7.8 | ± 0.8 | -1.86 | ± 0.19 |
J mol-1 K-1 | cal mol-1 K-1 | ||||
ΔS | = | 26.2 | ± 2.7 | 6.3 | ± 0.6 |
Detection Method: | Direct | ||
Assay Type: | Direct Binding Assay | ||
Technique: | Isothermal Titration Calorimetry | ||
Instrument: | Tronac Model 450 | ||
VCell | = | 2500.0 𝜇L | |
VSyringe | = | 1000.0 𝜇L | |
cmolecule | = | 3000.0 𝜇M cell | |
cpartner | = | 35000.0 𝜇M syringe |
Solvent System | Complex Mixture | |
Solvents | water | 50.0 % |
Formic acid | 50.0 % | |
Citation: |
H. Buschmann, K. Jansen, E. Schollmeyer, SupraBank 2024, The formation of cucurbituril complexes with amino acids and amino alcohols in aqueous formic acid studied by calorimetric titrations (dataset). https://doi.org/10.34804/supra.20230719481 |
Link: | https://doi.org/10.34804/supra.20230719481 |
Export: | BibTex | RIS | EndNote |
Citation: |
H.-J. Buschmann, K. Jansen, E. Schollmeyer, Thermochimica Acta 1998, 317, 95–98. |
Link: | https://doi.org/10.1016/S0040-6031(98)00377-3 |
Export: | BibTex | RIS | EndNote |
The plot depicts the binding isotherm simulation of a 1:1 interaction of glycine (0.004276245456489203 M) and CB6 (0 — 0.008552490912978406 M).