𝜈 | Molecule 1 : 1 Host | ||
Ka = | 616.6 | ± 28.4 | M-1 |
Kd = | |||
logKa = | |||
T | 25.0 °C | ||
Energy | kJ mol-1 | kcal mol-1 | |||
---|---|---|---|---|---|
ΔG | = | -15.93 | ± 0.11 | -3.81 | ± 0.03 |
ΔH | = | -2.3 | ± 0.4 | -0.55 | ± 0.1 |
-TΔS | = | -13.6 | ± 0.3 | -3.25 | ± 0.07 |
J mol-1 K-1 | cal mol-1 K-1 | ||||
ΔS | = | 45.6 | ± 1.0 | 10.9 | ± 0.2 |
Detection Method: | Direct | ||
Assay Type: | Direct Binding Assay | ||
Technique: | Isothermal Titration Calorimetry | ||
Instrument: | ITC | ||
Molecule: | syringe | ||
Partner: | cell |
Solvent System | Complex Mixture | |
Solvents | water | 50.0 % |
Formic acid | 50.0 % | |
Citation: |
H. Buschmann, E. Schollmeyer, K. Jansen, C. Meschke, SupraBank 2024, Thermodynamic Data for Complex Formation Between Cucurbituril and Alkali and Alkaline Earth Cations in Aqueous Formic Acid Solution (dataset). https://doi.org/10.34804/supra.20231010496 |
Link: | https://doi.org/10.34804/supra.20231010496 |
Export: | BibTex | RIS | EndNote |
Citation: |
H.-J. Buschmann, K. Jansen, C. Meschke, E. Schollmeyer, Journal of Solution Chemistry 1998, 27, 135–140. |
Link: | https://doi.org/10.1023/A:1022605306651 |
Export: | BibTex | RIS | EndNote |
The plot depicts the binding isotherm simulation of a 1:1 interaction of K+ (0.03243593902043464 M) and CB6 (0 — 0.06487187804086927 M).