Interaction Scheme
Molecule
Bis(5-carboxypentyl)-N,N'-bipyridiniium
Host
CB7
Binding Properties
| 𝜈 | Molecule 1 : 1 Host | ||
| Ka = | 4.90⋅105 | ± 6.00⋅104 | M-1 |
| Kd = | |||
| logKa = | |||
| T | 23.0 °C | ||
| Energy | kJ mol-1 | kcal mol-1 | |||
|---|---|---|---|---|---|
| ΔG | = | -32.26 | ± 0.3 | -7.71 | ± 0.07 |
These are the specifications of the determination of the experimental results.
| Detection Method: | Direct | |||
| Assay Type: | Direct Binding Assay | |||
| Technique: | Absorbance | |||
| 𝛌abs | = | 262.0 nm | ||
Detailed information about the solvation.
| Solvent System | Buffer System | 0.1 M NaCl pH-2.0 |
| Solvents | water | |
| Source of Concentration | estimated | |
| pH | 2.0 |
Please find here information about the dataset this interaction is part of.
| Citation: |
D. Sobransingh, V. Sindelar, S. Silvi, S. Parker, A. Kaifer, SupraBank 2024, Proton and Electron Transfer Control of the Position of Cucurbit[n]uril Wheels in Pseudorotaxanes (dataset). https://doi.org/10.34804/supra.20231115504 |
| Link: | https://doi.org/10.34804/supra.20231115504 |
| Export: | BibTex | RIS | EndNote |
Please find here information about the scholarly article describing the results derived from that data.
| Citation: |
V. Sindelar, S. Silvi, S. E. Parker, D. Sobransingh, A. E. Kaifer, Adv Funct Materials 2007, 17, 694–701. |
| Link: | https://doi.org/10.1002/adfm.200600969 |
| Export: | BibTex | RIS | EndNote |
Binding Isotherm Simulations
The plot depicts the binding isotherm simulation of a 1:1 interaction of Bis(5-carboxypentyl)-N,N'-bipyridiniium (4.0816326530612245e-05 M) and CB7 (0 — 8.163265306122449e-05 M).
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