Dataset curated

DOI:
https://doi.org/10.34804/supra.20210928106 Cc Cc by 4.0

Title:
Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes

https://pubs.acs.org/na101/home/literatum/publisher/achs/journals/content/jacsat/2017/jacsat.2017.139.issue-25/jacs.7b05021/20170622/images/large/ja-2017-05021v_0006.jpeg

Description:
Chiral epoxides are important intermediates in chemistry and biology. The high-throughput screening of asymmetric epoxidation conditions requires fast determination of the absolute configurations and ee values of chiral epoxides. Herein, we report molecular recognition and chiroptical sensing of epoxides in water using endo-functionalized molecular tubes. The absolute configurations and ee values were simultaneously determined by circular dichroism spectroscopy. In addition, real-time monitoring as well as the application to real asymmetric epoxidation was demonstrated. The method is simple, environmentally friendly, and amenable to high-throughput screening.

Citation:

H. Ke, W. Jiang, S. Wang, L. Wang, Z. Chen, W. Liu, SupraBank 2024, Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes (dataset). https://doi.org/10.34804/supra.20210928106

Link: https://doi.org/10.34804/supra.20210928106
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Citation:

L.-L. Wang, Z. Chen, W.-E. Liu, H. Ke, S.-H. Wang, W. Jiang, J. Am. Chem. Soc. 2017, 139, 8436–8439.

Link: https://doi.org/10.1021/jacs.7b05021
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Creators:
Orcidid | Ror | Li-Li Wang
Orcidid | Ror | Zhao Chen
Orcidid | Ror | Wei-Er Liu
Orcidid | Ror | Hua Ke
Orcidid | Ror | Sheng-Hua Wang
Orcidid | Ror | Wei Jiang

Contributers:
Orcidid | Ror | Amrutha Prabodh | DataManager

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