Dataset curated

DOI:
https://doi.org/10.34804/supra.20210928146 Cc Cc by 4.0

Title:
Highly Effective Binding of Methyl Viologen Dication and Its Radical Cation by p-Sulfonatocalix[4,5]arenes

https://pubs.acs.org/na101/home/literatum/publisher/achs/journals/content/joceah/2007/joceah.2007.72.issue-20/jo701304g/production/images/large/jo701304gn00001.jpeg

Description:
The binding behaviors and thermodynamic origins of p-sulfonatocalix[4]arene (C4AS) and p-sulfonatocalix[5]arene (C5AS) with methyl viologen (MV2+) have been investigated by the methods of isothermal titration calorimetry, NMR, and cyclic voltammetry, showing that the binding abilities of C4AS and C5AS and their host selectivity are dramatically pH-controlled, which is closely discussed from the viewpoint of thermodynamics. Moreover, the radical form of MV+• can also be effectively included by C4AS and C5AS.

Citation:

D. Guo, Y. Liu, L. Wang, SupraBank 2024, Highly Effective Binding of Methyl Viologen Dication and Its Radical Cation by p-Sulfonatocalix[4,5]arenes (dataset). https://doi.org/10.34804/supra.20210928146

Link: https://doi.org/10.34804/supra.20210928146
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Citation:

D.-S. Guo, L.-H. Wang, Y. Liu, J. Org. Chem. 2007, 72, 7775–7778.

Link: https://doi.org/10.1021/jo701304g
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Creators:
Orcidid | Ror | Dong-Sheng Guo
Orcidid | Ror | Li-Hua Wang
Orcidid | Ror | Yu Liu

Contributers:
Orcidid | Ror | Yu-Chen Pan | DataManager

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