Dataset curated
- DOI:
- https://doi.org/10.34804/supra.20210928265
- Title:
- Substituent effect and enthalpy-entropy compensation on the inclusion of?-cyclodextrin with 1-substituted naphthalenes
- Description:
- The inclusion complexation ofβ-CD with 1-substituted naphthalenes has been investigated by fluorescence spectroscopy. It was observed that the association constants were influenced by the molar refraction (R m), hydrophobic constant (π x ), and Hammett constant (σ x ) of substituents in the guest compounds. The thermodynamic parameters ΔG0, ΔH 0, and ΔS 0 determined by measuring the temperature-dependentK a values shows that inclusion complex formation is enthalpy driven. The results are discussed in terms of enthalpy-entropy compensation.
| Citation: |
Q. Guo, X. Zheng, X. Ruan, S. Luo, Y. Liu, SupraBank 2024, Substituent effect and enthalpy-entropy compensation on the inclusion of?-cyclodextrin with 1-substituted naphthalenes (dataset). https://doi.org/10.34804/supra.20210928265 |
| Link: | https://doi.org/10.34804/supra.20210928265 |
| Export: | BibTex | RIS | EndNote |
| Views | Downloads | Citations |
|---|---|---|
| 772 | 0 | 0 |
| Citation: |
Q.-X. Guo, X.-Q. Zheng, X.-Q. Ruan, S.-H. Luo, Y.-C. Liu, J Incl Phenom Macrocycl Chem 1996, 26, 175–183. |
| Link: | https://doi.org/10.1007/BF01053536 |
| Export: | BibTex | RIS | EndNote | |
- Creators:
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Qing-Xiang Guo
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Xiao-Qi Zheng
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Xiu-Qin Ruan
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Shuang-Hui Luo
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You-Cheng Liu
- Contributers:
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Joana Krämer
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DataManager
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