Dataset curated

DOI:
https://doi.org/10.34804/supra.20210928265 Cc Cc by 4.0

Title:
Substituent effect and enthalpy-entropy compensation on the inclusion of?-cyclodextrin with 1-substituted naphthalenes

https://media.springernature.com/w200/springer-static/cover/journal/10847.jpg

Description:
The inclusion complexation ofβ-CD with 1-substituted naphthalenes has been investigated by fluorescence spectroscopy. It was observed that the association constants were influenced by the molar refraction (R m), hydrophobic constant (π x ), and Hammett constant (σ x ) of substituents in the guest compounds. The thermodynamic parameters ΔG0, ΔH 0, and ΔS 0 determined by measuring the temperature-dependentK a values shows that inclusion complex formation is enthalpy driven. The results are discussed in terms of enthalpy-entropy compensation.

Citation:

Q. Guo, X. Zheng, X. Ruan, S. Luo, Y. Liu, SupraBank 2024, Substituent effect and enthalpy-entropy compensation on the inclusion of?-cyclodextrin with 1-substituted naphthalenes (dataset). https://doi.org/10.34804/supra.20210928265

Link: https://doi.org/10.34804/supra.20210928265
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Citation:

Q.-X. Guo, X.-Q. Zheng, X.-Q. Ruan, S.-H. Luo, Y.-C. Liu, J Incl Phenom Macrocycl Chem 1996, 26, 175–183.

Link: https://doi.org/10.1007/BF01053536
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Creators:
Orcidid | Ror | Qing-Xiang Guo
Orcidid | Ror | Xiao-Qi Zheng
Orcidid | Ror | Xiu-Qin Ruan
Orcidid | Ror | Shuang-Hui Luo
Orcidid | Ror | You-Cheng Liu

Contributers:
Orcidid | Ror | Joana Krämer | DataManager

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