Dataset curated

DOI:
https://doi.org/10.34804/supra.20211007405 Cc Cc by 4.0
Title:
A Comparison of the Host–Guest Inclusion Complexes of 1,8-ANS and 2,6-ANS in Parent and Modified Cyclodextrins - Journal of Inclusion Phenomena and Macrocyclic Chemistry
https://media.springernature.com/w200/springer-static/cover/journal/10847.jpg
Description:
The fluorescent molecules1-anilinonaphthalene-8-sulfonate (1,8-ANS) and2-anilinonaphthalene-6-sulfonate (2,6-ANS) areextremely sensitive to the polarity of their localenvironment, making them excellent probes for thestudy of heterogeneous systems, including cyclodextrin(CD) solutions. Both are only weakly fluorescent in ahighly polar medium, such as water, but are extremelyfluorescent in a relatively nonpolar medium, such aswithin a CD cavity. These two probes are isomers, withmajor structural differences: 1,8-ANS is much bulkierand more spherical, whereas 2,6-ANS is much morestreamlined and rod-shaped. Thus, they show majordifferences in their formation of CD inclusioncomplexes. This is reflected both in the magnitude ofthe observed fluorescence enhancement upon CDinclusion, as well as in the value of the associationconstant for complex formation. The creation of ascale for each probe for their fluorescence in CDsrelative to that in ethanol allows for directcomparisons to be made between the two probes. Theseresults are obtained and compared for the host-guestinclusion complexes of 1,8-ANS and 2,6-ANS with sixCDs: α, β, γ, and theirhydroxypropylated analogs.
Citation:

B. D. Wagner, S. J. Fitzpatrick, SupraBank 2024, A Comparison of the Host–Guest Inclusion Complexes of 1,8-ANS and 2,6-ANS in Parent and Modified Cyclodextrins - Journal of Inclusion Phenomena and Macrocyclic Chemistry (dataset). https://doi.org/10.34804/supra.20211007405

Link: https://doi.org/10.34804/supra.20211007405
Export: BibTex | RIS | EndNote
Views Downloads Citations
3405 0 0
Citation:

B. D. Wagner, S. J. Fitzpatrick, Journal of Inclusion Phenomena and Macrocyclic Chemistry 2000, 38, 467–478.

Link: https://doi.org/10.1023/A:1008198825835
Export: BibTex | RIS | EndNote
Creators:
Orcidid | Ror | Brian D. Wagner
Orcidid | Ror | Shannon J. Fitzpatrick
Contributers:
Orcidid | Ror | Changming Hu | DataManager

Included Interactions 8 Info

Show interactions per page
Default trans