Interaction

curated

Interaction Scheme

Molecule

3 4 7 8 tetramethyl 1 10 phenanthroline 1 7 bis 4%284' methyl 2 2' bipyridyl%29 heptane ruthenium%28ii%29
[3,4,7,8-tetramethyl-1,10-phenanthroline][1,7-...

c = 0.675 µM

Host

Cb10
CB10

c = 0.0 — 12.5 µM

Binding Properties

𝜈 Molecule 1 : 1 Host
Ka = 9.90⋅106 ± 0.2 M-1
Kd =
logKa = 7.0 ± 0.0
T 25.0 °C ≈ 298 K
Energy kJ mol-1 kcal mol-1
ΔG = -39.93 ± 0.0 -9.54 ± 0.0
Comment
emissions were recorded in the λ = 510–800 nm range
These are the specifications of the determination of the experimental results.
Detection Method: Direct
Assay Type: Direct Binding Assay
Technique: Fluorescence
𝛌ex = 435.0 nm
Detailed information about the solvation.
Solvent System Single Solvent
Solvent water
Please find here information about the dataset this interaction is part of.
Citation:

A. I. Day, B. Sun, I. F. Musgrave, K. Heimann, F. R. Keene, J. G. Collins, SupraBank 2024, Eukaryotic Cell Toxicity and HSA Binding of [Ru(Me4phen)(bb7)]2+ and the Effect of Encapsulation in Cucurbit[10]uril (dataset). https://doi.org/10.34804/supra.20220628439

Link: https://doi.org/10.34804/supra.20220628439
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Please find here information about the scholarly article describing the results derived from that data.
Citation:

B. Sun, I. F. Musgrave, A. I. Day, K. Heimann, F. R. Keene, J. G. Collins, Front. Chem. 2018, 6, DOI 10.3389/fchem.2018.00595.

Link: https://doi.org/10.3389/fchem.2018.00595
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Binding Isotherm Simulations

The plot depicts the binding isotherm simulation of a 1:1 interaction of [3,4,7,8-tetramethyl-1,10-phenanthroline][1,7-bis[4(4′-methyl-2,2′-bipyridyl)]heptane]ruthenium(II) (2.02020202020202e-06 M) and CB10 (0 — 4.04040404040404e-06 M).